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Factory Supply industrial standard MYRAC ALDEHYDE 37677-14-8 In Stock
- Molecular Formula: C13H20O
- Molecular Weight: 192.301
- Appearance/Colour: Clear Colorless to yellow oiliness liquid
- Vapor Pressure: 0.00565mmHg at 25°C
- Refractive Index: 1.524
- Boiling Point: 273.7 °C at 760 mmHg
- Flash Point: 96.1 °C
- PSA： 17.07000
- Density: 0.955 g/cm3
- LogP: 3.65820
MYRAC ALDEHYDE(Cas 37677-14-8) Usage
|
Preparation |
From myrcene and acrolein (Arctander, 1969). |
|
Hazard |
Low toxicity by ingestion. A moderate skin and mild eye irritant. |
|
Trade name |
Myrac aldehyde (IFF), Myraldene (Givaudan), Myracal (DRT). |
InChI:InChI=1/C13H20O/c1-11(2)4-3-5-12-6-8-13(10-14)9-7-12/h4,6,10,13H,3,5,7-9H2,1-2H3
37677-14-8 Relevant articles
Diels-Alder reaction of myrcene with carbonyl containing dienophiles supported on silica gel under microwave irradiation
Oskooie, Hossein Abdi
, p. 1165 - 1167 (2004)
Diels-Alder reactions of myrcene (7-meth...
The search for new odorants: Synthesis of animalic fragrant and musky/ambery compounds
Plessis, Caroline
, p. 1517 - 1539 (2015/03/03)
An overview of the recent research which...
Unsaturated aldehydes as alkene equivalents in the Diels-Alder reaction
Taarning, Esben,Madsen, Robert
supporting information; experimental part, p. 5638 - 5644 (2009/05/30)
A one-pot procedure is described for usi...
High regioselective Diels-Alder reaction of myrcene with acrolein catalyzed by zinc-containing ionic liquids
Yin, Donghong,Li, Changzhi,Li, Biaomo,Tao, Liang,Yin, Dulin
, p. 137 - 142 (2007/10/03)
The ambient zinc-containing ionic liquid...
37677-14-8 Process route
-
-
123-35-3
7-methyl-3-methene-1,6-octadiene
-
-
107-02-8,25068-14-8
acrolein
-
-
37677-14-8,80450-04-0
4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde
| Conditions | Yield |
|---|---|
|
With
silica gel;
at 25 ℃;
for 1h;
|
66%
|
|
With
β-Zeolite;
In
dichloromethane;
at 20 ℃;
for 4h;
|
22%
|
|
With
boron trifluoride diethyl etherate;
In
diethylene glycol dimethyl ether;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
|
|
|
With
aluminum (III) chloride;
In
toluene;
at 20 ℃;
for 16h;
|
-
-
123-35-3
7-methyl-3-methene-1,6-octadiene
-
-
107-02-8,25068-14-8
acrolein
-
-
37677-14-8,80450-04-0
4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde
-
-
52475-89-5
3-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde
| Conditions | Yield |
|---|---|
|
at 110 ℃;
|
|
|
silica gel;
at 20 ℃;
for 1h;
Yield given. Yields of byproduct given;
|
|
|
silica gel;
In
water;
for 0.166667h;
microwave irradiation;
|
|
|
With
1-butylpyridinium bromide; zinc(II) chloride;
at 15 ℃;
for 2h;
Further Variations:;
Reagents;
Solvents;
Product distribution;
|
37677-14-8 Upstream products
-
123-35-3
7-methyl-3-methene-1,6-octadiene
-
107-02-8
acrolein
37677-14-8 Downstream products
-
40772-93-8
(±)-[4-(4-methyl-3-pentenyl)-3-cyclohexen-1-yl]methanol
-
68991-97-9
(1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthalenecarboxyaldehyde)
-
73301-20-9
1-(4-methyl-3-pentenyl)cyclohexene
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