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[1S-(1alpha,2beta,3beta,5alpha)]-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
- CAS:35998-01-7
- purity:99%
Manufacturer supply good quality [1S-(1alpha,2beta,3beta,5alpha)]-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol 35998-01-7 with stock
- Molecular Formula: C10H18 O
- Molecular Weight: 154.252
- Boiling Point: 74.5 °C (3 mmHg)
- PSA: 20.23000
- LogP: 2.04940
35998-01-7 Relevant articles
Preparation of crystalline (diisopinocampheyl)borane
Abbott, Jason R.,Allais, Christophe,Roush, William R.
, p. 26 - 37 (2016/08/27)
-
Biology-oriented synthesis of a withanolide-inspired compound collection reveals novel modulators of hedgehog signaling
venda, Jakub,Sheremet, Michael,Kremer, Lea,Maier, Luk,Ziegler, Slava,Kumar, Kamal,Waldmann, Herbert,Bauer, Jonathan O.,Strohmann, Carsten
supporting information, p. 5596 - 5602 (2015/06/01)
Biology-oriented synthesis employs the s...
Synthesis and ultraviolet absorption characteristics of 4-arylidene isopinocamphones from α-pinene
Wang, Jia-Y.U.,Wang, Peng-N.A.,Yang, Jin-Lai,Shen, Jia,Xu,Wang, Shi-F. A.
, p. 7779 - 7784 (2015/02/02)
A new series of 4-arylidene isopinocamph...
Use of immobilized transition metal complexes as recyclable catalysts for oxidation reactions with hydrogen peroxide as oxidant
Islam, Sk Manirul,Mobarok, Manir,Mondal, Paramita,Roy, Anupam Singha,Salam, Noor,Hossain, Dildar,Mondal, Sanchita
experimental part, p. 97 - 107 (2012/09/22)
A tetradentate Schiff base (teta), obtai...
35998-01-7 Process route
-
-
7785-26-4,25766-18-1
(-)-α-pinene
-
-
1196-00-5,2734-31-8,19889-94-2,19889-95-3,25465-65-0,25465-95-6,27779-29-9,35997-96-7,35998-01-7,36129-11-0,51152-11-5,73366-08-2,125473-76-9,473-61-0,24041-60-9
(+)-isopinocampheol
| Conditions | Yield |
|---|---|
|
(-)-α-pinene;
With
dimethylsulfide borane complex;
In
tetrahydrofuran;
at 20 ℃;
With
sodium hydroxide; dihydrogen peroxide;
In
tetrahydrofuran; ethanol;
for 1h;
Heating;
|
90%
|
|
(-)-α-pinene;
With
1-bromo-butane; sodium tetrahydroborate; Aliquat 336;
at 20 ℃;
for 16h;
With
sodium hydroxide; dihydrogen peroxide;
at 40 ℃;
for 1h;
|
80%
|
|
With
dihydrogen peroxide; benzo[1,3,2]dioxaborole;
samarium (III) iodide;
Yield given. Multistep reaction;
1.) THF, r.t., 18 h;
|
|
|
With
hydroboron;
|
|
|
With
pyridine; oxygen; dichloroaluminum hydride;
triethyl borane;
Yield given. Multistep reaction;
1) 1,2-dichloroethane, RT, 2) RT, 3 h;
|
|
|
Multi-step reaction
with
2
steps
1: peroxybenzoic acid; diethyl ether
2: Raney nickel; ethanol / 85 °C / 36775.4 Torr / Hydrogenation
With
Perbenzoic acid; diethyl ether; ethanol; nickel;
|
-
-
19894-98-5
6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol
-
-
1196-00-5,2734-31-8,19889-94-2,19889-95-3,25465-65-0,25465-95-6,27779-29-9,35997-96-7,35998-01-7,36129-11-0,51152-11-5,73366-08-2,125473-76-9,473-61-0,24041-60-9
(+)-isopinocampheol
| Conditions | Yield |
|---|---|
|
With
palladium on activated charcoal; cyclohexane;
at 100 ℃;
under 62518.2 Torr;
Hydrogenation;
|
35998-01-7 Upstream products
-
19894-98-5
6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol
-
1686-14-2
(1R,2R,4S,6R)-2,7,7-trimethyl-3-oxatricyclo[4.1.1.0.2,4 ]octane
-
7785-26-4
(-)-α-pinene
-
110-82-7
cyclohexane
35998-01-7 Downstream products
-
14575-93-0
isopinocamphone
-
14575-99-6
phthalic acid mono-((1S :2S :3S )-pinanyl-(3) -ester)
-
5362-50-5
4-methyl-3-penten-1-al
-
36237-64-6
dihydrocarveol
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