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[1S-(1alpha,2beta,3beta,5alpha)]-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol

  • CAS:35998-01-7
  • purity:99%
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Manufacturer supply good quality [1S-(1alpha,2beta,3beta,5alpha)]-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol 35998-01-7 with stock

  • Molecular Formula: C10H18 O
  • Molecular Weight: 154.252
  • Boiling Point: 74.5 °C (3 mmHg) 
  • PSA: 20.23000 
  • LogP: 2.04940 

35998-01-7 Relevant articles

Preparation of crystalline (diisopinocampheyl)borane

Abbott, Jason R.,Allais, Christophe,Roush, William R.

, p. 26 - 37 (2016/08/27)

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Biology-oriented synthesis of a withanolide-inspired compound collection reveals novel modulators of hedgehog signaling

venda, Jakub,Sheremet, Michael,Kremer, Lea,Maier, Luk,Ziegler, Slava,Kumar, Kamal,Waldmann, Herbert,Bauer, Jonathan O.,Strohmann, Carsten

supporting information, p. 5596 - 5602 (2015/06/01)

Biology-oriented synthesis employs the s...

Synthesis and ultraviolet absorption characteristics of 4-arylidene isopinocamphones from α-pinene

Wang, Jia-Y.U.,Wang, Peng-N.A.,Yang, Jin-Lai,Shen, Jia,Xu,Wang, Shi-F. A.

, p. 7779 - 7784 (2015/02/02)

A new series of 4-arylidene isopinocamph...

Use of immobilized transition metal complexes as recyclable catalysts for oxidation reactions with hydrogen peroxide as oxidant

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experimental part, p. 97 - 107 (2012/09/22)

A tetradentate Schiff base (teta), obtai...

35998-01-7 Process route

(-)-α-pinene
7785-26-4,25766-18-1

(-)-α-pinene

(+)-isopinocampheol
1196-00-5,2734-31-8,19889-94-2,19889-95-3,25465-65-0,25465-95-6,27779-29-9,35997-96-7,35998-01-7,36129-11-0,51152-11-5,73366-08-2,125473-76-9,473-61-0,24041-60-9

(+)-isopinocampheol

Conditions
Conditions Yield
(-)-α-pinene; With dimethylsulfide borane complex; In tetrahydrofuran; at 20 ℃;
With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; ethanol; for 1h; Heating;
90%
(-)-α-pinene; With 1-bromo-butane; sodium tetrahydroborate; Aliquat 336; at 20 ℃; for 16h;
With sodium hydroxide; dihydrogen peroxide; at 40 ℃; for 1h;
80%
With dihydrogen peroxide; benzo[1,3,2]dioxaborole; samarium (III) iodide; Yield given. Multistep reaction; 1.) THF, r.t., 18 h;
With hydroboron;
With pyridine; oxygen; dichloroaluminum hydride; triethyl borane; Yield given. Multistep reaction; 1) 1,2-dichloroethane, RT, 2) RT, 3 h;
Multi-step reaction with 2 steps
1: peroxybenzoic acid; diethyl ether
2: Raney nickel; ethanol / 85 °C / 36775.4 Torr / Hydrogenation
With Perbenzoic acid; diethyl ether; ethanol; nickel;
6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol
19894-98-5

6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol

(+)-isopinocampheol
1196-00-5,2734-31-8,19889-94-2,19889-95-3,25465-65-0,25465-95-6,27779-29-9,35997-96-7,35998-01-7,36129-11-0,51152-11-5,73366-08-2,125473-76-9,473-61-0,24041-60-9

(+)-isopinocampheol

Conditions
Conditions Yield
With palladium on activated charcoal; cyclohexane; at 100 ℃; under 62518.2 Torr; Hydrogenation;

35998-01-7 Upstream products

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    (-)-α-pinene

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    cyclohexane

35998-01-7 Downstream products

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    4-methyl-3-penten-1-al

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